A couple of podcasts I've bumped into that are useful:
Rune Soup: extremely high quality, well thought out interviews on a variety of topics. Just great for general occult knowledge. Slight bias toward old school Chaos Magic.
New World Witchery: hit and miss so far, but when it's a hit, it's a hit. Mix of high quality folk interviews, essays and slightly undirected witch friends chatting on skype. Focused on American folk magic traditions.

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